2025

1. Structural Engineering of Au−Ag Heterometallic Nanoparticles Using Multidentate Polyoxometalate Ligands
   K. Xia,* T. Yatabe, K. Yonesato, K. Kawakami, S. Kikkawa, S. Yamazoe, K. Yamaguchi, K. Suzuki*
   Small, in press.
   
2. Selective Imine Synthesis by Acceptorless Dehydrogenative Coupling of Alcohols and Amines via Cooperative Catalysis of Basic-Polyoxometalate-Decorated Ag Nanoparticles on Al₂O₃
   S. Fukuda, S. Kikkawa,* K. Suzuki, K. Yamaguchi, H. Kawasoko, S. Yamazoe*
   ChemCatChem., in press.
   DOI: 10.1002/cctc.202501240
3. Homoleptic and Heteroleptic Polyoxotungstate–Organic Cages for Efficient Photocatalytic Hydrogen Evolution
   W. Ruan, Y. Feng, Y. Gao, K. Yonesato, L. Lan, P. Yin, M. Wang, K. Suzuki,* H. Lv,* X. Fang*
   Angew. Chem. Int. Ed., 64, e202508797 (2025).
   DOI: 10.1002/anie.202508797
4. Surface-Exposed Pd Nanocluster Confined within a Ring-Shaped Polyoxometalate for Selective Hydrogenation
   R. Xi, K. Yonesato, T. Yatabe, Y. Koizumi, S. Kikkawa, S. Yamazoe, K. Harano, K. Yamaguchi, K. Suzuki*
   Adv. Sci., 12, e09418 (2025).
   DOI: 10.1002/advs.202509418
5. Synthesis of a Keggin-type polyoxoselenidotungstate via site-selective oxygen-to-selenium substitution
   K. Yonesato,* Y. Watanabe, M. Pascual-Borràs, R. J. Errington, K. Yamaguchi, K. Suzuki*
   Chem. Sci., 16, 13183–13188 (2025).
   DOI: 10.1039/D5SC03340C
6. Engineering cofacial porphyrin dimers using lacunary polyoxotungstates
   M. Yamaguchi, K. Yonesato, K. Shioya, C. Li, K. Murata, K. Ishii,* K. Yamaguchi,* K. Suzuki*
   Chem. Sci., 16, 9178–9185 (2025).
   DOI: 10.1039/d5sc00814j
7. Catalytic methane oxidation to methanol using supported Cu-introduced polyoxometalate cesium salt catalysts
   T. Suzuki, T. Yabe,* K. Suzuki, K. Yamaguchi,*
   Chem. Lett., 54, upaf077 (2025).
   DOI: 10.1093/chemle/upaf077
8. Ligand-directed bottom-up synthesis of trivacant lacunary polyoxomolybdates in organic media
   A. Jimbo, C. Li, K. Yonesato, K. Yamaguchi, K. Suzuki,*
   Chem. Lett., 54, upaf072 (2025).
   DOI: 10.1093/chemle/upaf072
9. Ligand-directed top-down synthesis of trivacant lacunary polyoxomolybdates from plenary Keggin-type [α-XMo₁₂O_40]^3– (X = P, As, V) in organic media
   A. Jimbo, C. Li, K. Yonesato, K. Yamaguchi, K. Suzuki,*
   Dalton Trans., 54, 8234–8240 (2025).
   DOI: 10.1039/D5DT00252D
10. Mechanochemical Templated Synthesis of Mesoporous Alumina-Supported Polyoxometalate Catalysts toward Selective Oxidation of Sulfides
    K. Xia, S. Hou, Q. Niu, K. Suzuki, P. Zhang,*
    RSC Mechanochem., 2, 394-398 (2025).
    DOI: 10.1039/D4MR00130C
11. In-situ QXAFS study on CO and H₂ adsorption on Pt in solid [PtAu₈(PPh₃)₈]-H[PMo₁₂O₄₀]
    T. Matsuyama, T. Suzuki, Y. Oba, S. Kikkawa, S. Uchida, J. Ohyama, K. Higashi, T. Kaneko, K. Kato, K. Nitta, T. Uruga, K. Hatada, K. Yoshikawa, A. Heilmaier, K. Suzuki, K. Yonesato, K. Yamaguchi, N. Nakatani, H. Kawasoko, S. Yamazoe,*
    Nanoscale, 17, 2480–2487 (2025).
    DOI: 10.1039/D4NR03785E

2024

1. Heteroatom Effect on Site-Selective Oxygen–Sulfur Substitution Reactions of Keggin-type Polyoxotungstates
   Y. Watanabe, K. Yonesato,* D.Yokogawa, K. Yamaguchi, K. Suzuki,*
   Inorg. Chem., 63, 23388–23395 (2024).
   DOI: 10.1021/acs.inorgchem.4c04149
2. Electronic state modulation of Ag₃₀ nanoclusters within a ring-shaped polyoxometalate
   D. Yanai, K. Yonesato,* S. Kikkawa, S. Yamazoe, K. Yamaguchi, K. Suzuki,*
   Nanoscale, 16, 18383–18388 (2024).
   DOI: 10.1039/D4NR02547D
3. Pd-incorporated polyoxometalate catalysts for electrochemical CO₂ reduction
   K. Kawakami, T. Yabe, F. Amano, K. Yamaguchi, K. Suzuki,*
   Chem. Sci., 15, 14829–14836 (2024).
   DOI: 10.1039/D4SC04304A
4. Synthesis of a Gold–Silver Alloy Nanocluster within a Ring-Shaped Polyoxometalate and Its Photocatalytic Property
   M. Kamachi, K. Yonesato,* T. Okazaki, D. Yanai, S. Kikkawa, S. Yamazoe, R. Ishikawa, N. Shibata, Y. Ikuhara, K. Yamaguchi, K. Suzuki,*
   Angew. Chem. Int. Ed., 63, e202408358 (2024).
   DOI: 10.1002/anie.202408358
5. Synthesis of polyoxothiometalates through site-selective post-editing sulfurization of polyoxometalates
   K. Yonesato,* K. Yamaguchi, K. Suzuki,*
   Chem. Sci., 15, 11267–11271 (2024).
   DOI: 10.1039/D4SC02912G
6. Multidentate polyoxometalate modification of metal nanoparticles with tunable electronic states
   K. Xia, T. Yatabe, K. Yamaguchi, K. Suzuki,*
   Dalton Trans., 53, 11088–11093 (2024).
   DOI: 10.1039/D4DT01218F
7. Self-assembled molecular hybrids comprising lacunary polyoxometalates and multidentate imidazole ligands
   H. Sun, A. Jimbo, C. Li, K. Yonesato, K. Yamaguchi, K. Suzuki,*
   Chem. Sci., 15, 9281–9286 (2024).
   DOI: 10.1039/D4SC02384F
8. Small Copper Nanoclusters Synthesized through Solid-State Reduction inside a Ring-Shaped Polyoxometalate Nanoreactor
   Y. Koizumi, K. Yonesato, S. Kikkawa, S. Yamazoe, K. Yamaguchi, K. Suzuki,*
   J. Am. Chem. Soc., 146, 14610–14619 (2024).
   DOI: 10.1021/jacs.4c01661
9. Photocatalytic aerobic α-oxygenation of amides to imides using a highly durable decatungstate tetraphenylphosphonium salt
   C. Gu, T. Yatabe, K. Yamaguchi, K. Suzuki,*
   Chem. Commun., 60, 4906–4909 (2024).
   DOI: 10.1039/D4CC01016G
10. A density functional study on the photocatalytic degradation of polycaprolactone by decatungstate anion in acetonitrile solution
    N. Minezawa, K. Suzuki, S. Okazaki,*
    Phys. Chem. Chem. Phys., 26, 11746–11754 (2024).
    DOI: 10.1039/D4CP00362D
11. Multi-stimuli-responsive polymer degradation by polyoxometalate photocatalysis and chloride ion
    C. Gu, C. Li, N. Minezawa, S. Okazaki,* K. Yamaguchi, K. Suzuki,*
    Nanoscale, 16, 8013–8019 (2024).
    DOI: 10.1039/D4NR00394B
12. Ultra-stable and highly reactive colloidal gold nanoparticle catalysts protected using multi-dentate metal oxide nanoclusters
    K. Xia, T. Yatabe, K. Yonesato, S. Kikkawa, S. Yamazoe, A. Nakata, R. Ishikawa, N. Shibata, Y. Ikuhara, K. Yamaguchi, K. Suzuki,*
    Nat. Commun., 15, 851 (2024).
    DOI: 10.1038/s41467-024-45066-9
13. Porphyrin–Polyoxotungstate Molecular Hybrid as a Highly Efficient, Durable, Visible-Light-Responsive Photocatalyst for Aerobic Oxidation Reactions
    M. Yamaguchi, K. Shioya, C. Li, K. Yonesato, K. Murata, K. Ishii,* K. Yamaguchi,* K. Suzuki,*
    J. Am. Chem. Soc., 146, 4549–4556 (2024).
    DOI: 10.1021/jacs.3c11394

2023

1. Highly efficient degradation of polyesters and polyethers by decatungstate photocatalysis
   C. Li, C. Gu, K. Yamaguchi, K. Suzuki,*
   Nanoscale, 15, 15038–15042 (2023).
   DOI: 10.1039/D3NR03978A
2. Molecular hybrids of trivacant lacunary polyoxomolybdate and multidentate organic ligands
   A. Jimbo, C. Li, K. Yonesato, T. Ushiyama, K. Yamaguchi, K. Suzuki,*
   Chem. Sci., 14, 10280–10284 (2023).
   DOI: 10.1039/d3sc03713d
3. Investigating the Antiviral Properties of Copper- and Silver-containing Polyoxometalates using a High-throughput Screening Method
   K. Yonesato,* M. Nakakido,* K. Tsumoto,* Y. Egami, N. Miyamae, T. Wakihara, K. Suzuki, K. Yamaguchi,*
   Chem. Lett., 52, 678–681 (2023).
   DOI: 10.1246/cl.230264
4. Role of polyoxometalate precursors and supports in the selective oxidation of methane into formaldehyde using supported metal oxide subnanocluster catalysts
   K. Wachi, T. Yabe,* T. Suzuki, K. Yonesato, K. Suzuki, K. Yamaguchi,*
   Catal. Sci. Technol., 13, 4744–4752 (2023).
   DOI: 10.1039/D3CY00750B
5. Surface-exposed silver nanoclusters inside molecular metal oxide cavities
   K. Yonesato, D. Yanai, S. Yamazoe, D. Yokogawa, T. Kikuchi, K. Yamaguchi,* K. Suzuki,*
   Nat. Chem., 15, 940–947 (2023).
   DOI: 10.1038/s41557-023-01234-w
6. Creation of Highly Dispersed Supported Polyoxometalate Cesium Salts via Cation Exchange from Alkylammonium Salts on Supports
   T. Suzuki, T. Yabe,* K. Wachi, K. Yonesato, K. Suzuki, K. Yamaguchi,*
   ChemNanoMat, 9, e202200428 (2023).
   DOI: 10.1002/cnma.202200428

2022

1. Coordination of Palladium(II) and Platinum(II) Complexes to One Vacant Site in an α-Keggin-Type Polyoxotungstate
   N. Kato,* S. Ishigaki, R. Kasai, T. Mizuno, K. Suzuki,
   Inorg. Chem., 61, 9445–9453 (2022).
   DOI: 10.1021/acs.inorgchem.2c00203
2. {Mo₁₂₆W₃₀}: Polyoxometalate Cages Shaped by π-π Interactions
   M. Zhu, S. Han, J. Liu, M. Tan, W. Wang, K. Suzuki, P. Yin, D. Xia, X. Fang,*
   Angew. Chem. Int. Ed., 61, e202213910 (2022).
   DOI: 10.1002/anie.202213910
3. Dual functional catalysis of [Nb₆O₁₉]^8--modified Au/Al₂O₃
   S. Kikkawa, S. Fukuda, J. Hirayama, N. Shirai, R. Takahata, K. Suzuki, K. Yamaguchi, T. Teranishi, S. Yamazoe,*
   Chem. Commun., 58, 9018–9021 (2022).
   DOI: 10.1039/D2CC02472A
4. Ligand-Protecting Strategy for Controlled Construction of Multinuclear Copper Cores within Ring-Shaped Polyoxometalate
   Y. Koizumi, K. Yonesato, K. Yamaguchi,* K. Suzuki,*
   Inorg. Chem., 61, 9841–9848 (2022).
   DOI: 10.1021/acs.inorgchem.2c01029
5. Supported Anionic Gold Nanoparticle Catalysts Modified Using Highly Negatively Charged Multivacant Polyoxometalates
   K. Xia, T. Yatabe, K. Yonesato, T. Yabe, S. Kikkawa, S. Yamazoe, A. Nakata, K. Yamaguchi,* K. Suzuki,*
   Angew. Chem. Int. Ed., 61, e202205873 (2022).
   DOI: 10.1002/anie.202205873
6. Selective oxidation of methane into formaldehyde and carbon monoxide catalyzed by supported thermally stable iron oxide subnanoclusters prepared from a diiron-introduced polyoxometalate precursor
   K. Wachi, T. Yabe,* T. Suzuki, K. Yonesato, K. Suzuki, K. Yamaguchi,*
   Appl. Catal. B Environ., 314, 121420 (2022).
   DOI: 10.1016/j.apcatb.2022.121420
7. Variable control of the electronic states of a silver nanocluster via protonation/deprotonation of polyoxometalate ligands
   K. Yonesato, S. Yamazoe, S. Kikkawa, D. Yokogawa, K. Yamaguchi,* K. Suzuki,*
   Chem. Sci., 13, 5557–5561 (2022).
   DOI: 10.1039/D2SC01156E
8. Cu/N-oxyl-catalyzed aerobic oxidative esterification to oxalic acid diesters from ethylene glycol via highly selective intermolecular alcohol oxidation
   Y. Morino, T. Yatabe,* K. Suzuki, K. Yamaguchi,*
   Green Chem., 24, 2017–2026 (2022).
   DOI: 10.1039/D1GC04001D
9. Nanostructured Manganese Oxides within a Ring-Shaped Polyoxometalate Exhibiting Unusual Oxidation Catalysis
   K. Sato, K. Yonesato, T. Yatabe, K. Yamaguchi,* K. Suzuki,*
   Chem. Eur. J., 28, e202104051 (2022).
   DOI: 10.1002/chem.202104051

2021

1. Robotic Stepwise Synthesis of Hetero-Multinuclear Metal Oxo Clusters as Single-Molecule Magnets
   T. Minato, D. Salley, N. Mizuno, K. Yamaguchi, L. Cronin,* K. Suzuki,*
   J. Am. Chem. Soc., 143, 12809–12816 (2021).
   DOI: 10.1021/jacs.1c06047
2. Synthesis of a phosphomolybdate with a tetranuclear vanadium core by installing vanadium atoms in a lacunary template using protecting group strategy
   C. Li, K. Yamaguchi,* K. Suzuki,*
   Chem. Commun., 57, 6530–6533 (2021).
   DOI: 10.1039/D1CC03099JE
3. A Molecular Hybrid of an Atomically Precise Silver Nanocluster and Polyoxometalates for H₂ Cleavage into Protons and Electrons
   K. Yonesato, S. Yamazoe, D. Yokogawa, K. Yamaguchi,* K. Suzuki,*
   Angew. Chem. Int. Ed., 60, 16994–16998 (2021).
   DOI: 10.1002/anie.202106786
4. Heterogeneously Ni–Pd nanoparticle-catalyzed base-free formal C–S bond metathesis of thiols
   K. Mitamura, T. Yatabe,* K. Yamamoto, T. Yabe, K. Suzuki, K. Yamaguchi,*
   Chem. Commun., 57, 3749–3752 (2021).
   DOI: 10.1039/D1CC00995H
5. Ligand-Directed Approach in Polyoxometalate Synthesis: Formation of a New Divacant Lacunary Polyoxomolybdate [γ-PMo₁₀O₃₆]⁷⁻
   C. Li, K. Yamaguchi,* K. Suzuki,*
   Angew. Chem. Int. Ed., 60, 6960–6964 (2021).
   DOI: 10.1002/anie.202016642
6. A protecting group strategy to access stable lacunary polyoxomolybdates for introducing multinuclear metal clusters
   C. Li, A. Jimbo, K. Yamaguchi,* K. Suzuki,*
   Chem. Sci., 12, 1240–1244 (2021).
   DOI:10.1039/d0sc06133f

2020

1. Thermal Treatment of a Keggin-Type Diplatinum(II)-Coordinated Polyoxotungstate: Formation of Hydrophilic Colloidal Particles and Photocatalytic Hydrogen Production
   N. Kato,* K. Aono, A. Kurihara, T. Kubota, R. Kasai, K. Suzuki,
   Eur. J. Inorg. Chem., 3917–3924 (2020).
   DOI: 10.1002/ejic.202000638
2. Supersilyl as an Effective Monodentate Ligand to Stabilize Four-Coordinate Manganese(II) Complexes
   S. Arata, K. Suzuki, K. Yamaguchi, Y. Sunada,*
   Dalton Trans., 49, 17537–17541 (2020).
   DOI: 10.1039/d0dt03837g
3. An Ultrastable, Small {Ag₇}⁵⁺ Nanocluster within a Triangular Hollow Polyoxometalate Framework
   K. Yonesato, H. Ito, D. Yokogawa, K. Yamaguchi,* K. Suzuki,*
   Angew. Chem. Int. Ed., 59, 16361–16365 (2020).
   DOI: 10.1002/anie.202008402
4. Selectivity switch in the aerobic oxygenation of sulfides photocatalysed by visible-light-responsive decavanadate
   C. Li, N. Mizuno, K. Murata, K. Ishii, T. Suenobu, K. Yamaguchi*, K. Suzuki,*
   Green Chem., 22, 3896–3905 (2020).
   DOI: 10.1039/D0GC01500H

2019

1. Controlled Assembly Synthesis of Atomically Precise Ultrastable Silver Nanoclusters with Polyoxometalates
   K. Yonesato, H. Ito, H. Itakura, D. Yokogawa, T. Kikuchi, N. Mizuno, K. Yamaguchi,* K. Suzuki,*
   J. Am. Chem. Soc., 141, 19550–19554 (2019).
   DOI: 10.1021/jacs.9b10569
2. Methyl Selective α-Oxygenation of Tertiary N-Methylamines to Formamides by Employing Copper/Moderately Hindered Nitroxyl Radical (DMN-AZADO or 1-Me-AZADO)
   S. Nakai, T. Yatabe, K. Suzuki, Y. Sasano, Y. Iwabuchi, J. Hasegawa, N. Mizuno, K. Yamaguchi,*
   Angew. Chem. Int. Ed., 58, 16651–16659 (2019).
   DOI: 10.1002/anie.201909005
3. Self-Assembly of Anionic Polyoxometalate–Organic Architectures Based on Lacunary Phosphomolybdates and Pyridyl Ligands
   C. Li, N. Mizuno, K. Yamaguchi,* K. Suzuki,*
   J. Am. Chem. Soc., 141, 7687–7692 (2019).
   DOI: 10.1021/jacs.9b02541
4. Ring-Shaped Polyoxometalates Possessing Multiple 3d Metal Cation Sites: [{M₂(OH₂)₂}₂{M(OH₂)₂}₄P₈W₄₈O₁₇₆(OCH₃)₈]¹⁶⁻ (M = Mn, Ni, Co, Cu, or Zn)
   S. Sasaki, K. Yonesato, N. Mizuno, K. Yamaguchi,* K. Suzuki,*
   Inorg. Chem., 58, 7722–7729 (2019).
   DOI: 10.1021/acs.inorgchem.9b00061
5. Exploring orientationally aligned anisotropic large spin molecules with unusual long-distance intermolecular ferromagnetic interactions
   T. Minato, Y. Ohata, K. Ishii, K. Yamaguchi, N. Mizuno, K. Suzuki,*
   Mater. Chem. C, 7, 12918–12925 (2019).
   DOI: 10.1039/C9TC00740G
6. Hexavacant γ-Dawson-type phosphotungstates supporting an edge-sharing bis(square-pyramidal) {O₂M(μ₃-O)₂(μ-OAc)MO₂} core (M = Mn²⁺, Co²⁺, Ni²⁺, Cu²⁺, or Zn²⁺)
   K. Suzuki,* T. Minato, N. Tominaga, I. Okumo, K. Yonesato, N. Mizuno, K. Yamaguchi,*
   Dalton Trans., 48, 7281–7289 (2019).
   DOI: 10.1039/C8DT04850A

2018

1. Porous Cubic Cesium Salts of Silicododecatungstate(molybdate)/Borododecatungstate Blends: Synthesis and Molecular Adsorption Properties
   T. Kotabe, Y. Ogasawara,* K. Suzuki, S. Uchida, N. Mizuno, K. Yamaguchi,*
   Inorg. Chem., 57, 8821–8830 (2018).
   DOI: 10.1021/acs.inorgchem.8b00657
2. Effect of Heteroatoms on Field-Induced Slow Magnetic Relaxation of Mononuclear Fe^III (S = 5/2) Ions within Polyoxometalates
   T. Minato, D. Aravena,* E. Ruiz, K. Yamaguchi, N. Mizuno, K. Suzuki,*
   Inorg. Chem., 57, 6957–6964 (2018).
   DOI: 10.1021/acs.inorgchem.8b00644
3. Polyoxometalate LUMO engineering: a strategy for visible-light-responsive aerobic oxygenation photocatalysts
   C. Li, K. Suzuki,* N. Mizuno, K. Yamaguchi,*
   Chem. Commun., 54, 7127–7130 (2018).
   DOI: 10.1039/C8CC03519A
4. CuCl/TMEDA/nor-AZADO-catalyzed aerobic oxidative acylation of amides with alcohols to produce imides
   K. Kataoka, K. Wachi, X. Jin,* K. Suzuki, Y. Sasano, K. Iwabuchi, J. Hasegawa, N. Mizuno, K. Yamaguchi,*
   Chem. Sci., 9, 4756–4768 (2018).
   DOI: 10.1039/C8SC01410H
5. Aerobic Oxygenation of Alkylarenes over Ultrafine Transition-Metal-Containing Manganese-Based Oxides,
   S. Nakai, T. Uematsu, Y. Ogasawara, K. Suzuki, K. Yamaguchi,* N. Mizuno,*
   ChemCatChem, 10, 1096–1106 (2018).
   DOI: 10.1002/cctc.201701587

2017

1. Visible-light-responsive catalysis of a zinc-introduced lacunary disilicoicosatungstate for deoxygenation of pyridine N-oxides
   J. Jeong, K. Suzuki,* K. Yamaguchi,* N. Mizuno,*
   New J. Chem., 41, 13226–13229 (2017).
   DOI: 10.1039/C7NJ03057F
2. Alkoxides of Trivacant Lacunary Polyoxometalates
   T. Minato, K. Suzuki,* K. Yamaguchi, N. Mizuno,*
   Chem. Eur. J., 23, 14213–14220 (2017).
   DOI: 10.1002/chem.201702883
3. Photoredox Catalysis of Visible-light-responsive Divacant Lacunary Silicotungstate for Reduction of Aldehydes
   K. Suzuki,* K. Yamaguchi, N. Mizuno,*
   Chem. Lett., 46, 1379–1382 (2017).
   DOI: 10.1246/cl.170577
4. A modular synthesis approach to multinuclear heterometallic oxo clusters in polyoxometalates
   T. Minato, K. Suzuki,* Y. Ohata, K. Yamaguchi, N. Mizuno,*
   Chem. Commun., 53, 7533–7536 (2017).
   DOI: 10.1039/C7CC04072E
5. Creation of bismuth–tungsten oxide nanoclusters using lacunary polyoxometalates
   T. Hanaya, K. Suzuki,* R. Sato, K. Yamaguchi, N. Mizuno,*
   Dalton Trans., 46, 7384–7387 (2017).
   DOI: 10.1039/C7DT01587A
6. Platinum-supporting hollandite-type vanadium–chromium mixed oxides as efficient heterogeneous catalysts for deoxygenation of sulfoxides under atmospheric H₂ pressure
   T. Uematsu, Y. Ogasawara, K. Suzuki, K. Yamaguchi,* N. Mizuno,*
   Catal. Sci. Technol., 7, 1912–1920 (2017).
   DOI: 10.1039/C7CY00547D
7. Release and catch catalysis by tungstate species for the oxidative cleavage of olefins
   Y. Yoshimura, Y. Ogasawara,* K. Suzuki, K. Yamaguchi,* N. Mizuno,*
   Catal. Sci. Technol., 7, 1662–1670 (2017).
   DOI: 10.1039/C7CY00062F
8. Phosphovanadomolybdic acid catalyzed direct C–H trifluoromethylation of (hetero)arenes using NaSO₂CF₃ as the CF₃ source and O₂ as the terminal oxidant
   C. Li, K. Suzuki, K. Yamaguchi,* N. Mizuno,*
   New J. Chem., 41, 1417–1420 (2017).
   DOI: 10.1039/C6NJ03654F

2016

1. Selective Deoxygenation of Pyridine N-Oxides through Photoredox Catalysis of a Dilacunary Silicotungstate
   J. Jeong, K. Suzuki, M. Hibino, K. Yamaguchi, N. Mizuno,*
   ChemistrySelect, 1, 5042–5048 (2016).
   DOI: 10.1002/slct.201601146
2. Hexanuclear tin(II) and mixed valence tin(II,IV) oxide clusters within polyoxometalates
   K. Suzuki, T. Hanaya, R. Sato, T. Minato, K. Yamaguchi, N. Mizuno,*
   Chem. Commun., 52, 10688–10691 (2016).
   DOI: 10.1039/C6CC05284C
3. Organozirconium Complex with Keggin-type Mono-aluminum-substituted Silicotungstate: Synthesis, Molecular Structure, and Catalytic Performance for Meerwein-Ponndorf-Verley Reduction
   N. Kato,* W. Unno, S. Kato, T. Ogasawara, T. Kashiwagi, H. Uno, K. Suzuki, N. Mizuno,
   Catal. Lett., 146, 2119–2128 (2016).
   DOI: 10.1007/s10562-016-1813-7
4. Synthesis and Disassembly/Reassembly of Giant Ring-Shaped Polyoxotungstate Oligomers
   T. Minato, K. Suzuki, K. Yamaguchi, N. Mizuno,*
   Angew. Chem. Int. Ed., 55, 9630–9633 (2016).
   DOI: 10.1002/anie.201604094
5. Rational Low-Temperature Synthesis of Ultrasmall Nanocrystalline Manganese Binary Oxide Catalysts under Controlled Metal Cation Hydration in Organic Media
   Y. Miyamoto, Y. Kuroda, T. Uematsu, H. Oshikawa, N. Shibata, Y. Ikuhara, K. Suzuki, M. Hibino, K. Yamaguchi, N. Mizuno,*
   ChemNanoMat, 2, 297–306 (2016).
   DOI: 10.1002/cnma.201600114
6. Phosphovanadomolybdic acids catalyzed desulfurization‒oxygenation of secondary and tertiary thioamides into amides using molecular oxygen as the terminal oxidant
   N. Xu, X. Jin, K. Suzuki, K. Yamaguchi, N. Mizuno,*
   New. J. Chem., 40, 4865–4869 (2016).
   DOI: 10.1039/C5NJ03579A
7. Water- and Temperature-Triggered Reversible Structural Transformation of Tetranuclear Cobalt(II) Cores Sandwiched by Polyoxometalates
   Y. Kuriyama, Y. Kikukawa, K. Suzuki, K. Yamaguchi, N. Mizuno,*
   Chem. Eur. J., 22, 3962–3966 (2016).
   DOI: 10.1002/chem.201600139
8. Sequential Synthesis of 3d-3d’-4f Heterometallic Heptanuclear Clusters in between Lacunary Polyoxometalates
   R. Sato, K. Suzuki, T. Minato, K. Yamaguchi, N. Mizuno,*
   Inorg. Chem., 55, 2023–2029 (2016).
   DOI: 10.1021/acs.inorgchem.5b02358
9. Synthesis of N-Acylsulfenamides through Aerobic Cross Dehydrogenative Coupling of Thiols and Amides by Supported Copper Hydroxide Catalyst
   K. Sakagami, X. Jin, K. Suzuki, K. Yamaguchi, N. Mizuno,*
   Chem. Lett., 45, 173–175 (2016).
   DOI: 10.1246/cl.151090
10. Photoredox catalysis for oxygenation/deoxygenation between sulfides and sulfoxides by visible-light-responsive polyoxometalates
    K. Suzuki, J. Jeong, K. Yamaguchi, N. Mizuno,*
    New J. Chem., 40, 1014–1021 (2016).
    DOI: 10.1039/C5NJ01045D
11. Molybdenum-doped α-MnO₂ as an efficient reusable heterogeneous catalyst for aerobic sulfide oxygenation
    T. Uematsu, Y. Miyamoto, Y. Ogasawara, K. Suzuki, K. Yamaguchi, N. Mizuno,*
    Catal. Sci. Technol., 6, 222–233 (2016).
    DOI: 10.1039/C5CY01552A

2015

1. Synthesis of ultrasmall Li–Mn spinel oxides exhibiting unusual ion exchange, electrochemical, and catalytic properties
   Y. Miyamoto, Y. Kuroda, T. Uematsu, H. Oshikawa, N. Shibata, Y. Ikuhara, K. Suzuki, M. Hibino, K. Yamaguchi, N. Mizuno,*
   Sci. Rep., 5, 15011 (2015).
   DOI: 10.1038/srep15011
2. Synthesis and oxidation catalysis of a Ti-substituted phosphotungstate, and identification of the active oxygen species
   R. Takahashi, K. Kamata, Y. Kikukawa, S. Sato, K. Suzuki, K. Yamaguchi, N. Mizuno,*
   Catal. Sci. Technol., 5, 4778–4789 (2015).
   DOI: 10.1039/C5CY01031D
3. Regioselective direct oxidative C–H cyanation of quinolone derivatives catalyzed by vanadium-containing heteropoly acids
   K. Yamaguchi, N. Xu, X. Jin, K. Suzuki, N. Mizuno,*
   Chem. Commun., 51, 10034–10037 (2015).
   DOI: 10.1039/C5CC02797G
4. Synthesis and structural characterization of BINOL-modified chiral polyoxometalates
   R. Ishimoto, K. Kamata, K. Suzuki, K. Yamaguchi, N. Mizuno,*
   Dalton Trans., 44, 10947–10951 (2015).
   DOI: 10.1039/C5DT01338K
5. A cascade approach to hetero-pentanuclear manganese-oxide clusters in polyoxometalates and their single-molecule magnet properties
   K. Suzuki, R. Sato, T. Minato, M. Shinoe, K. Yamaguchi, N. Mizuno,*
   Dalton Trans., 44, 14220–14226 (2015).
   DOI: 10.1039/C5DT01363A
6. Synthesis, Structural Characterization, and Oxidation Catalysis of a Diniobium-substituted Silicodecatungstate
   N. Satake, T. Hirano, K. Kamata, K. Suzuki, K. Yamaguchi, N. Mizuno,*
   Chem. Lett., 44, 899–901 (2015).
   DOI: 10.1246/cl.150213
7. Selective Oxidation with Aqueous Hydrogen Peroxide by [PO₄{WO(O₂)₂}₄]^3– Supported on Zinc-Modified Tin Dioxide
   S. Nojima, K. Kamata, K. Suzuki, K. Yamaguchi, N. Mizuno,*
   ChemCatChem, 7, 1097–1104 (2015).
   DOI: 10.1002/cctc.201402975
8. Field-Induced Slow Magnetic Relaxation of Octahedrally Coordinated Mononuclear Fe(III)-, Co(II)-, and Mn(III)-Containing Polyoxometalates
   R. Sato, K. Suzuki,* T. Minato, M. Shinoe, K. Yamaguchi, N. Mizuno,*
   Chem. Commun., 51, 4081–4084 (2015).
   DOI: 10.1039/C4CC09435B
9. Composites of [γ-H₂PV₂W₁₀O₄₀]^3– and [α-SiW₁₂O₄₀]^4– supported on Fe₂O₃ as heterogeneous catalysts for selective oxidation with aqueous hydrogen peroxide
   Y. Wan, K. Kamata, R. Ishimoto, Y. Ogasawara, K. Suzuki, K. Yamaguchi, N. Mizuno,*
   Catal. Sci. Technol., 5, 2602–2611 (2015).
   DOI: 10.1039/C4CY01693A
10. Visible-Light-Responsive Multielectron Redox Catalysis of Lacunary Polyoxometalates Induced by Substrate Coordination to Their Lacuna
    K. Suzuki, J. Jeong, K. Yamaguchi, N. Mizuno,*
    Chem. Asian J., 10, 144–148 (2015).
    DOI: 10.1002/asia.201403072
11. Hydrogen Evolution Using the Visible-Light-Induced Metal-to-Polyoxometalate Multiple Electron Transfer
    K. Suzuki, F. Tang, Y. Kikukawa, K. Yamaguchi, N. Mizuno,*
    Chem. Lett., 43, 1429–1431 (2015).
    DOI: 10.1246/cl.140450

Before

1. Visible-Light-Induced Photoredox Catalysis with a Tetracerium-Containing Silicotungstate
   K. Suzuki, F. Tang, Y. Kikukawa, K. Yamaguchi, N. Mizuno,*
   Angew. Chem. Int. Ed., 53, 5356–5360 (2014).
   DOI: 10.1002/anie.201403215
2. Synthesis of α-Dawson-Type Silicotungstate [Si₂W₁₈O₆₂]^8– and Protonation and Deprotonation Inside the Aperture via Intramolecular Hydrogen Bonds
   T. Minato, K. Suzuki, K. Kamata, N. Mizuno,*
   Chem. Eur. J., 20, 5946–5952 (2014).
   DOI: 10.1002/chem.201400390
3. Heterodinuclear Lanthanoid-Containing Polyoxometalates: Stepwise Synthesis and Single-Molecule Magnet Behavior
   R. Sato, K. Suzuki, M. Sugawa, N. Mizuno,*
   Chem. Eur. J., 19, 12982–12990 (2013).
   DOI: 10.1002/chem.201302596
4. Synthesis, Structure Characterization, and Reversible Transformation of a Cobalt Salt of a Dilacunary γ-Keggin Silicotungstate and Sandwich-Type Di- and Tetra-Cobalt-Containing Silicotungstate Dimers
   Y. Kikukawa, K. Suzuki, K. Yamaguchi, N. Mizuno,*
   Inorg. Chem., 52, 8664–8652 (2013).
   DOI: 10.1021/ic4008075
5. Reversible switching of single-molecule magnet behaviors by transformation of dinuclear dysprosium cores in polyoxometalates
   K. Suzuki, R. Sato, N. Mizuno,*
   Chem. Sci., 4, 596–600 (2013).
   DOI: 10.1039/C2SC21619A
6. A discrete octahedrally shaped [Ag₆]⁴⁺ cluster encapsulated within silicotungstate ligands
   Y. Kikukawa, Y. Kuroda, K. Suzuki, M. Hibino, K. Yamaguchi, N. Mizuno,*
   Chem. Commun., 49, 376–378 (2013).
   DOI: 10.1039/C2CC37591E
7. Synthesis and Reversible Transformation of Cu_n-Bridged (n = 1, 2, or 4) Silicodecatungstate Dimers
   K. Suzuki, M. Shinoe, N. Mizuno,*
   Inorg. Chem., 51, 11574–11581 (2012).
   DOI: 10.1021/ic301488a
8. Strategic Design and Refinement of Lewis Acid-Base Catalysis by Rare-Earth-Metal-Containing Polyoxometalates
   K. Suzuki, M. Sugawa, Y. Kikukawa, K. Kamata, K. Yamaguchi, N. Mizuno,*
   Inorg. Chem., 51, 6953–6961 (2012).
   DOI: 10.1021/ic3008365
9. Cyanosilylation of Carbonyl Compounds with Trimethylsilyl Cyanide by Yttrium-Pillared Silicotungstate Dimer
   Y. Kikukawa, K. Suzuki, M. Sugawa, T. Hirano, K. Kamata, K. Yamaguchi, N. Mizuno,*
   Angew. Chem. Int. Ed., 51, 3686–3689 (2012).
   DOI: 10.1002/anie.201200486
10. Three-Dimensional Ordered Arrays of 58×58×58 ų Hollow Frameworks in Ionic Crystals of M₂Zn₂-Substituted Polyoxometalates
    K. Suzuki, Y. Kikukawa, S. Uchida, H. Tokoro, K. Imoto, S. Ohkoshi, N. Mizuno,*
    Angew. Chem. Int. Ed., 51, 1597–1601 (2012).
    DOI: 10.1002/anie.201107041
11. Protein Encapsulation within Synthetic Molecular Hosts
    D. Fujita, K. Suzuki, S. Sato, M. Yagi-Utsumi, Y. Yamaguchi, N. Mizuno, T. Kumasaka, M. Takata, M. Noda, S. Uchiyama, K. Kato, M. Fujita,*
    Nat. Commun., 3, 1093 (2012).
    DOI: 10.1038/ncomms2093
12. Incarceration of (PdO)_n and Pd_n Clusters via Cage-Templated Synthesis of Hollow Silica Nanoparticles
    K. Takao, K. Suzuki, T. Ichijo, S. Sato, H. Asakura, K. Teramura, K. Kato, T. Ohba, T. Morita, M. Fujita,*
    Angew. Chem. Int. Ed., 51, 5893–5896 (2012).
    DOI: 10.1002/anie.201201288
13. Emission Color Trajectory and White Electroluminescence Through Supramolecular Control of Energy Transfer and Exciplex Formation in Binary Blends of Conjugated Polyrotaxanes
    S. Brovelli, G. Sforazzini, M. Serri, G. Winroth, K. Suzuki, F. Meinardi, H. L. Anderson,* F. Cacialli,*
    Adv. Funct. Mater., 22, 4284–4291 (2012).
    DOI: 10.1002/adfm.201200786
14. Synthesis of a Bridging Ligand with a Non-Denatured Protein Pendant: Toward Protein Encapsulation in a Coordination Cage
    D. Fujita, K. Suzuki, S. Sato, M. Yagi-Utsumi, E. Kurimoto, Y. Yamaguchi, K. Kato, M. Fujita,*
    Chem. Lett., 41, 313–315 (2012).
    DOI: 10.1246/cl.2012.313
15. The Precise Synthesis and Growth of Core–Shell Nanoparticles within a Self-Assembled Spherical Template
    K. Suzuki, K. Takao, S. Sato, M. Fujita,*
    Angew. Chem. Int. Ed., 50, 4858–4861 (2011).
    DOI: 10.1002/anie.201006965
16. Coronene Nanophase within Coordination Spheres: Increased Solubility of C₆₀
    K. Suzuki, K. Takao, S. Sato, M. Fujita,*
    J. Am. Chem. Soc., 132, 2544–2545 (2010).
    DOI: 10.1021/ja910836h
17. Template synthesis of precisely monodisperse silica nanoparticles within self-assembled organometallic spheres
    K. Suzuki, S. Sato, M. Fujita,*
    Nat. Chem., 2, 25–29 (2010).
    DOI: 10.1038/nchem.446
18. Self-assembly of an M₆L₁₂ coordination cube,
    K. Suzuki, M. Tominaga, M. Kawano, M. Fujita,*
    Chem. Commun., 1638–1640 (2009).
    DOI: 10.1039/b822311d
19. Discrete and Well-Defined Hydrophobic Phases Confined in Self-Assembled Spherical Complexes
    K. Suzuki, J. Iida, S. Sato, M. Kawano, M. Fujita,*
    Angew. Chem. Int. Ed., 47, 5780–5782 (2008).
    DOI: 10.1002/anie.200801700
20. Endohedral Peptide Lining of a Self-Assembled Molecular Sphere To Generate Chirality-Confined Hollows
    K. Suzuki, M. Kawano, S. Sato, M. Fujita,*
    J. Am. Chem. Soc., 129, 10652–10653 (2007).
    DOI: 10.1021/ja073629b
21. Solvato-Controlled Assembly of Pd₃L₆ and Pd₄L₈ Coordination Boxes
    K. Suzuki, M. Kawano, M. Fujita,*
    Angew. Chem. Int. Ed., 46, 2819–2822 (2007).
    DOI: 10.1002/anie.200605084
22. Fluorous Nanodroplets Structurally Confined in an Organopalladium Sphere
    S. Sato, J. Iida, K. Suzuki, M. Kawano, T. Ozeki, M. Fujita,*
    Science, 313, 1273–1276 (2006).
    DOI: 10.1126/science.1129830
23. 24-Fold Endohedral Functionalization of a Self-assembled M₁₂L₂₄ Coordination Nanoball
    M. Tominaga, K. Suzuki, T. Murase, M. Fujita,*
    J. Am. Chem. Soc., 127, 11950–11951 (2007).
    DOI: 10.1021/ja054069o